SCOM 2012 - Monitoring Applications + Performance

Dears,

My customer have Applications deployed on his windows server, and he wants to monitor this application.

The applications drop into 2 kinds:

• Web application (Not Java) its HTML with ASP or PHP coding with Databases
• 32 Bit Applications with Databases

I want to know below:

1. A link that help me to determine the applicable applications for monitoring (I need to determine this before deploying SCOM).
2. For performance monitoring, A link that help me to know if I can monitor the performance or not.

Thanks